Prepare the Baking Dish: Preheat the oven to 350°F. Generously spray a 9×13 baking dish with nonstick cooking spray, ensuring all sides are well coated to prevent sticking, as this dessert is quite sticky when baked.
Create the Pecan Filling: Add 2 cups dark brown sugar, dark corn syrup, ½ cup melted butter, eggs, and vanilla to a medium-sized mixing bowl (2-3 quarts). Whisk thoroughly until the mixture is smooth and all ingredients are well incorporated, making sure there are no clumps of brown sugar remaining.
Add Pecans to Filling: Stir in 3 cups of pecan halves until they're evenly distributed throughout the mixture. Pour this rich pecan filling into the prepared baking dish, spreading it evenly to cover the entire bottom of the pan.
Layer the Cake Mix: Sprinkle the dry cake mix evenly over the pecan filling, creating a uniform layer that completely covers the pecan mixture beneath. Be careful not to mix the layers together.
Add Butter Layer: Drizzle the remaining ¾ cup of melted butter over the dry cake mix, trying to cover as much of the cake mix as possible to ensure proper moisture during baking.
Add Brown Sugar Layer: Sprinkle the remaining ¾ cup dark brown sugar evenly over the butter layer, distributing it across the entire surface for a caramelized finish.
Add Water Layer: Pour the hot water over the top of the layered ingredients. Do not stir or mix. You can carefully tilt the baking dish to help distribute the water more evenly over the cake mix if needed.
Add Pecan Topping: Sprinkle the remaining 1 cup pecan halves over the cake and water layer, arranging them for an attractive presentation after baking.
Bake to Perfection: Bake for 35-40 minutes or until the top is golden brown. The center will still be slightly jiggly when done, but it will firm up as it cools. Allow the cake to cool completely before serving for the best texture and flavor.